Redox potential, calculated using the Nernst equation, accounts for the stoichiometry of two electron transfers as two GSH are involved in the oxidation to GSSG ( h Cys/CySS and E h GSH/GSSG in serum is that it provides an overall measure of the pro-oxidant/anti-oxidant balance ( Fitzpatrick and colleagues have measured the E h Cys/CySS and E h GSH/GSSH of mild-to-moderate and severe asthmatics ( h Cys/CySS 65 mV) have a significantly more oxidized Cys/CySS redox potential than mild-to-moderate asthmatics (mean E h Cys/CySS 95 mV) and are similarly oxidized to severe asthmatics in the Fitzpatrick study (mean E h Cys/CySS 55 mV)
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1 H NMR (600 MHz, CD 3 OD) 6.26 (app s, 1 H), 6.25 (app d, J = 1.8 Hz, 1 H), 5.70 (dd, J = 5.1, 6.9 Hz, 1 H), 4.15 (app tt, J = 4.4, 9.1 Hz, 1 H), 3.40 (ddd, J = 0.7, 3.9, 13.6 Hz, 1 H), 3.35 (s, 1 H), 3.29 (app dd, J = 4.6, 6.2 Hz, 1 H), 3.183.23 (m, 2 H), 2.032.11 (m, 1 H), 1.952.02 (m, 1 H), 1.841.95 (m, 2 H), 1.731.81 (m, 1 H), 1.611.70 (m, 1 H)
