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The dual HPLC and mass-spec approach is the correct standard, since purity and identity are separate questions and a compound can be pure yet incorrectly identified

Still, neither peptide is approved for cosmetic use, and neither is considered particularly safe when acquired outside of a medical setting

References Adam E, Mller H, Erlacher A, Berg G (2016) Complete genome sequences of the Serratia plymuthica strains 3Rp8 and 3Re4-18, tworhizosphere bacteria with antagonistic activity towards fungal phytopathogens and plant growth-promoting abilities

Long-term side effects are uncommon when its used responsibly